Whereas, when the quantity of formaldehyde taken is more than that of phenol in the reacting mixture, and the reaction occurs in a basic medium, the condensation product is known as Resol. Centuries later the Iron Age introduced iron as the material of choice. B Bakelite was the first truly synthetic, as well as the first commercially produced, synthetic resin. Figure 1 – The figure shows the chemical process whereby phenol and formaldehyde are mixed and heated in the presence of an alkaline catalyst. Bakelite is a polymer made up of the monomers phenol and formaldehyde. Change ), NT Conradie - 19673418 [4], Image: https://www2.chemistry.msu.edu/faculty/reusch/virttxtjml/polymers.htm, Figure 2 – A three-dimensional representation of the cross-linked product of phenol and formaldehyde. (c) It has a coiled structure and chains held together by weak van der waals forces (d) It has fibrous structure and reactive sites at various double bonds. Answer: (c) It has a coiled structure and chains held together by weak van der waals forces (b) Bakelite is a condensation polymer. The characteristics of Bakelite made it particularly suitable as a molding compound, an adhesive or binding agent, a varnish, and a protective coating. On the basis of structures of polymers… [6], When phenol (C6H6O), which is an organic compound[1] and a common disinfectant[3], is mixed with formaldehyde (CH2O) in the presence of an alkali catalyst and heat[2], an exothermic reaction results. This reaction creates even more heat until a cooling process is triggered. [1] Bakelite’s characteristics include having low electrical conductivity and high heat and chemical resistance. (a) Bakelite (b) Teflon (c) Butyl rubber (d) Melamine formaldehyde resin Solution: (a, d) Bakelite is a condensation polymer of phenol and formaldehyde. Bakelite was the first truly synthetic, as well as the first commercially produced, synthetic resin. The ease of molding polymers into different shapes and their relatively low cost of production has been the main reason for their universal usage. Very smooth molding can be obtained from this polymer. Q:-What is crystal field splitting energy? Bakelite was particularly suitable for the emerging electrical and automobile industries because of its extraordinarily high resistance to electricity, heat, and chemical action. Answer/Explanation. ( Log Out / (a) Heavily branched cross linked polymers, (b) Linear slightly branched long chain molecules. Polymers are large molecules that have a structure of repeating units, often producing a strength that makes them ideal for construction. Polymers. Bakelite was patented on December 7, ... Polyurethanes are in the class of compounds called reaction polymers, which include epoxies, unsaturated polyesters, ... and the cross-linking reaction is commonly referred to as curing. Join BYJU’S or download our app to know more about polymers with the most simplified approach of learning. Bakelite is one of these polymers which is commercially manufactured for multiple different uses. How does the magnitude of Δ o decide the actual configuration of d-orbitals in a coordination entity?. Change ), You are commenting using your Twitter account. Bakelite, formed from the condensation reaction of phenol with formaldehyde, became hugely popular – perhaps you have seen products with Bakelite, such as … Question 14. When the phenol is taken in excess and the reaction medium is made acidic, the product of the condensation reaction obtained is acidic. These desired properties include: better mouldability, greater toughness and strength, and greater heat-, water-, chemical-, and shock-resistance. [2] The new mixture is then forced into heated moulds under high pressure. The chemical formula of bakelite can be written as (C6H6O-CH2OH)n. Some important properties of bakelite are listed below. New York: Marshall Cavendish. New Page 1. (2016). II. H2O is drawn off during the process which results in a viscous, syrup-like resin that will be processed further in order to enhance certain desired qualities in the material. It can also be made into different colours, but this depends on filler that it is mixed with during the manufacturing process. Some 5,000 years ago, we learned how to make alloys of copper, and the Bronze Age began. This phenol-formaldehyde resin is a thermosetting polymer. It is produced through condensation reaction between phenol and formaldehyde in the presence of either basic or acidic catalyst. Bakelite is the commercial name for the polymer obtained by the polymerization of phenol and formaldehyde. We are surrounded by objects, most of which, some way or the other have a polymer associated with them. Phenolic resins are also extensively used as adhesives and binding agents. Bakelite is made up of Phenol and formaldehyde. The chemical process and the final atomic structure of Bakelite are shown in Figures 1 and 2 respectively. A nylon umbrella over your head is used to move out of the house in heavy sunlight or to keep out of the r… S Meyer - 16719794 These polymers are depicted as follows: Based on Mode of Polymerisation: Polymers can also be classified on the basis of mode of polymerisation into two subgroups. History is shaped by the materials we develop and use. Write the names and structures of monomers of bakelite. Bakelite was the first FRP discovered by Dr. Baekeland. This resin is then poured into containers and is left to harden. Bakelite is a space-network polymer. ( Log Out / Further, Bakelite has been used for making the handles of a variety of utensils. In the first half of the 20th century they were made into very important plastics such as Bakelite … bakelite, melamine, etc. Bakelite is used for making electrical switches and switch boards. We are surrounded by objects, most of which, some way or the other have a polymer associated with them. (a) Dacron is obtained by heating terephthalic acid with ethylene glycol at 425–475 K. It is a condensation polymer. A hard, infusible, and chemically resistant plastic, Bakelite was based on a chemical combination of phenol and formaldehyde (phenol-formaldehyde resin), two compounds that were derived from coal tar and wood alcohol (methanol), respectively, at that time. A polymer sample contains 30%(by weight) of chains with molecular weight 10000, 30%(by weight) of the chains with molecular weight 20000, and the rest of chains with molecular weight 30000. Recently Viewed Questions of Class 12th chemistry. Bakelite moldings are heat-resistant and scratch-resistant. Bakelite. Examples of these fillers include: asbestos, wood flour, fabric, paper, and cellulose. Change ), You are commenting using your Facebook account. [online] Available at: American Chemical Society. Some of the plastic structures are drawn below. Monomers join together to form a long straight chain with some branched chains of different lengths. JJ Rossouw - 18961371 As a result of these branches, the polymers are not closely packed together. It is a thermosetting phenol-formaldehyde resin formed by the condensation reaction of phenol with formaldehyde. A thermosetting plastic is a plastic that liquefies and is malleable when heated. [6] Bakelite was the first truly synthetic, as well as the first commercially produced, synthetic resin. In general, phenol taken in excess acts as the cross-linking agent. ( Log Out / And Novolac on heating with formaldehyde undergoes cross linking to … Bakelite First Synthetic Plastic – National Historic Chemical Landmark – American Chemical Society. Once hard, it is crushed into a powder, which is then mixed with various fillers. It is a thermosetting plastic. The starting monomers of bakelite are phenol and formaldehyde i.e.Bakelite is a thermosetting polymer. [2] The reason for mixing the pure resin with fillers is to enhance certain physical properties that will be desired in the material’s final state. So, we can, in general, say that Bakelite is a condensation polymer or a phenolic resin. Author has 535 answers and 3M answer views Bakelite is an early polymer, comprised of a phenol-formaldehyde mixture, with Phenol being derived from coal tar, and Formaldehyde derived from methanol. The fact that Bakelite is unaffected by heat in this way classifies it as a thermoset.[5]. Now coming to the uses of Bakelite, since this element has a low electrical conductivity and high heat resistance it can be used in manufacturing electrical switches and machine parts of electrical systems. It was developed by the Belgian-American chemist Leo Baekeland in New York in 1907. The first synthetic polymer, a phenol-formaldehyde polymer, was introduced under the name “Bakelite Bakelite was originally used to make billiard balls. (d) Soften on heating and harden on cooling, can be reused. Inventors and inventions. The resultant polymers—known as phenol-formaldehyde resin, urea-formaldehyde resin, and melamine-formaldehyde resin—are widely used as adhesives in plywood and other structural wood products. Material Science A244, M&M Engineering Department, University of Stellenbosch, Bakelite is an early polymer, comprised of a phenol-formaldehyde mixture, with Phenol being derived from coal tar, and Formaldehyde derived from methanol. Fill in your details below or click an icon to log in: You are commenting using your WordPress.com account. (i) Linear polymer: These polymers consist of long and straight chains. Structure Bakelite is an early polymer, comprised of a phenol-formaldehyde mixture, with Phenol being derived from coal tar, and Formaldehyde derived from methanol. “Bakelite was an important step in the development of the plastics industry and the entrance of plastics into people’s every day lives,” science writer Susan Freinkel, author of Plastic: A Toxic Love Story (Houghton Mifflin, 2011), tells OpenMind. They are also resistant to several destructive solvents. As such, Bakelite is one of the commercially manufactured polymers that we witness in our daily lives. Each polymer chain will … The introduction of Bakelitethe worlds first synthetic plasticin 1907 marked the introduction of the Polymer Age. (2008). We cannot deny the presence of polymers in our lives. Elvenkrafte.com. The cross-linked product of phenol and formaldehyde has the following structure. Bakelite is a thermosetting phenol formaldehyde resin, developed in 1907–1909 by Belgian chemist Dr. Leo Baekeland. [1], Image: https://en.wikipedia.org/wiki/Phenol_formaldehyde_resin. Plastic: All the plastic materials are organic polymers with a repeating unit called monomer. As the title describes, the structure of these polymers is like branches originating at random points from a single linear chain. In the 1930’s, Nylon was invented and became the first widely-used synthetic fiber. The vast majority of these polymers are formed from chains of carbon atoms, 'pure' or with the addition of: oxygen, nitrogen, or sulfur. For thousands of years, humans used stone to fashion tools. Phenol is made to react with formaldehyde. (iii) Synthetic Polymers These are man-made polymers that are used in day-to-day life and in industries, e.g., plastic (polythene), synthetic fibres (nylon-6,6) and synthetic rubbers (Buna-S), etc. CBSE Previous Year Question Papers Class 10, CBSE Previous Year Question Papers Class 12, NCERT Solutions Class 11 Business Studies, NCERT Solutions Class 12 Business Studies, NCERT Solutions Class 12 Accountancy Part 1, NCERT Solutions Class 12 Accountancy Part 2, NCERT Solutions For Class 6 Social Science, NCERT Solutions for Class 7 Social Science, NCERT Solutions for Class 8 Social Science, NCERT Solutions For Class 9 Social Science, NCERT Solutions For Class 9 Maths Chapter 1, NCERT Solutions For Class 9 Maths Chapter 2, NCERT Solutions For Class 9 Maths Chapter 3, NCERT Solutions For Class 9 Maths Chapter 4, NCERT Solutions For Class 9 Maths Chapter 5, NCERT Solutions For Class 9 Maths Chapter 6, NCERT Solutions For Class 9 Maths Chapter 7, NCERT Solutions For Class 9 Maths Chapter 8, NCERT Solutions For Class 9 Maths Chapter 9, NCERT Solutions For Class 9 Maths Chapter 10, NCERT Solutions For Class 9 Maths Chapter 11, NCERT Solutions For Class 9 Maths Chapter 12, NCERT Solutions For Class 9 Maths Chapter 13, NCERT Solutions For Class 9 Maths Chapter 14, NCERT Solutions For Class 9 Maths Chapter 15, NCERT Solutions for Class 9 Science Chapter 1, NCERT Solutions for Class 9 Science Chapter 2, NCERT Solutions for Class 9 Science Chapter 3, NCERT Solutions for Class 9 Science Chapter 4, NCERT Solutions for Class 9 Science Chapter 5, NCERT Solutions for Class 9 Science Chapter 6, NCERT Solutions for Class 9 Science Chapter 7, NCERT Solutions for Class 9 Science Chapter 8, NCERT Solutions for Class 9 Science Chapter 9, NCERT Solutions for Class 9 Science Chapter 10, NCERT Solutions for Class 9 Science Chapter 12, NCERT Solutions for Class 9 Science Chapter 11, NCERT Solutions for Class 9 Science Chapter 13, NCERT Solutions for Class 9 Science Chapter 14, NCERT Solutions for Class 9 Science Chapter 15, NCERT Solutions for Class 10 Social Science, NCERT Solutions for Class 10 Maths Chapter 1, NCERT Solutions for Class 10 Maths Chapter 2, NCERT Solutions for Class 10 Maths Chapter 3, NCERT Solutions for Class 10 Maths Chapter 4, NCERT Solutions for Class 10 Maths Chapter 5, NCERT Solutions for Class 10 Maths Chapter 6, NCERT Solutions for Class 10 Maths Chapter 7, NCERT Solutions for Class 10 Maths Chapter 8, NCERT Solutions for Class 10 Maths Chapter 9, NCERT Solutions for Class 10 Maths Chapter 10, NCERT Solutions for Class 10 Maths Chapter 11, NCERT Solutions for Class 10 Maths Chapter 12, NCERT Solutions for Class 10 Maths Chapter 13, NCERT Solutions for Class 10 Maths Chapter 14, NCERT Solutions for Class 10 Maths Chapter 15, NCERT Solutions for Class 10 Science Chapter 1, NCERT Solutions for Class 10 Science Chapter 2, NCERT Solutions for Class 10 Science Chapter 3, NCERT Solutions for Class 10 Science Chapter 4, NCERT Solutions for Class 10 Science Chapter 5, NCERT Solutions for Class 10 Science Chapter 6, NCERT Solutions for Class 10 Science Chapter 7, NCERT Solutions for Class 10 Science Chapter 8, NCERT Solutions for Class 10 Science Chapter 9, NCERT Solutions for Class 10 Science Chapter 10, NCERT Solutions for Class 10 Science Chapter 11, NCERT Solutions for Class 10 Science Chapter 12, NCERT Solutions for Class 10 Science Chapter 13, NCERT Solutions for Class 10 Science Chapter 14, NCERT Solutions for Class 10 Science Chapter 15, NCERT Solutions for Class 10 Science Chapter 16, Important Questions For Class 11 Chemistry, Important Questions For Class 12 Chemistry, Difference Between Baking Soda And Baking Powder, CBSE Previous Year Question Papers Class 10 Science, CBSE Previous Year Question Papers Class 12 Physics, CBSE Previous Year Question Papers Class 12 Chemistry, CBSE Previous Year Question Papers Class 12 Biology, ICSE Previous Year Question Papers Class 10 Physics, ICSE Previous Year Question Papers Class 10 Chemistry, ICSE Previous Year Question Papers Class 10 Maths, ISC Previous Year Question Papers Class 12 Physics, ISC Previous Year Question Papers Class 12 Chemistry, ISC Previous Year Question Papers Class 12 Biology. You hop across the nylon carpet to the kitchen, eat your breakfast on a nylon bowl after cleaning your teeth with a toothbrush whose bristles are made of nylon. (2016). This is the chemical structure of Bakelite. [online] Available at. Bakelite | chemical compound. Q:-Calculate the osmotic pressure in pascals exerted by a solution prepared by dissolving 1.0 g of polymer of molar mass 185,000 in 450 mL of water at 37°C. Although polymers were first invented in the 1860’s, it was not mass-produced until the early 1900’s when Bakelite was used as a replacement for wood, ivory, tortoise-shell, etc. Calculate the number average and weight average molecular weight of the sample. Water and steam are then drawn off as the mixture cools, and a viscous brown resin remains. Cross-linked or Network polymers: These are usually formed from bi-functional and tri-functional monomers and contain strong covalent bonds between various linear polymer chains, e.g. It is a thermosetting phenol-formaldehyde resin formed by the condensation reaction of phenol with formaldehyde. HJG Van Zyl - 18300111, https://www2.chemistry.msu.edu/faculty/reusch/virttxtjml/polymers.htm, https://en.wikipedia.org/wiki/Phenol_formaldehyde_resin, http://www.elvenkrafte.com/bakelite%20presentation.htm, https://www.acs.org/content/acs/en/education/whatischemistry/landmarks/bakelite.html, https://global.britannica.com/science/Bakelite. The condensation reaction of the two reactants in a controlled acidic or basic medium results in the formation of ortho and para hydroxymethyl phenols and their derivatives. So, we can, in general, say that Bakelite is a condensation polymer or a phenolic resin. (c) Become infusible on moulding so cannot be reused. Answer. (2016). Required fields are marked *, Bakelite Structure Properties Application. Structure. Here ethylene (ethene) is the monomer, and the corresponding linear polymer is called high-density polyethylene (HDPE). from Chemistry Polymers Class 12 Haryana Board - English Medium. Change ), You are commenting using your Google account. [online] Available at: Wikipedia. Owing to its low electrical conductivity, bakelite is resistant to electric current. Bakelite, which is also known as a 'material of a thousand uses' is chemically called polyoxybenzyl methylene glycol anhydride. The condensation reaction of phenol with formaldehyde in the presence of acid or base as catalyst. Ltd. Download books and chapters from book store. The structure of bisphenol-A diglycidyl ether epoxy resin is … Bakelite is the trade name for phenol formaldehyde resin. Most plastics contain organic polymers. Bakelite, which is also known as a 'material of a thousand uses' is chemically called polyoxybenzyl methylene glycol anhydride. This phenol-formaldehyde resin is a thermosetting polymer. ( Log Out / Answer: Explaination: (a) and (c) e.g. These are one of the oldest polymers that were synthesized by man. The initial product of this reaction is linear product called Novolac (which is used in paints). This resin is then poured into containers and is left to harden. The preparation of bakelite involves several steps, as illustrated below. We cannot deny the presence of polymers in our lives. The starting monomers of bakelite are phenol and formaldehyde i.e.Bakelite is a thermosetting polymer. They are further used for protective purposes as well as in the coating industry. Melamine formaldehyde resin is a condensation polymer of melamine (2, 4, 6-triamino-1, 3, 5-triazine) and formaldehyde. Which of the following polymers are condensation polymers? These intermediate condensation products are used as resins in different industries. Initial methods of preparing bakelite involved the heating of formaldehyde and phenol in the presence of one of the following catalysts -zinc chloride (ZnCl2), hydrochloric acid (HCl), or ammonia (NH3). Your email address will not be published. After this final setting of the material it will not be possible to heat and reshape it again. Along came Bakelite – which is the first example of a truly synthetic polymer (the rest were just modifications of cellulose). Structure of Bakelite As we now know the Bakelite preparation method as well as its structure, let us now have a look at the properties of Bakelite. Nylon is the most useful synthetic material with applications varying from daily life activities to industries. It is a thermosetting polymer and Bakelite has high strength meaning it basically retains its form even after extensive molding. HDPE is composed of macromolecules in which n ranges from 10,000 to … When chemists began to recognize that many natural resins and fibers were polymers, Baekeland investigated the reactions of phenol and formaldehyde. What are the Desirable Properties of Bakelite? Preparation of Bakelite For polyethylene, arguably the simplest polymer, this is demonstrated by the following equation. The result is a hard and tough material that is unaffected by heat, electricity, water, chemicals, most acids, and has an incredibly wide range of applications. Unlike linear and branched polymers, which are composed of long molecules that make them more or less crystalline, space-network polymers are highly and irregularly cross-linked throughout the structure. It is one of the most common and important polymers that are used to make different parts of many objects. He first produced a soluble phenol-formaldehyde resin called “Novolak,” which never became a market success. To which class, thermoplastic and thermosetting does bakelite belong? CH 2 O) n. Its chemical name is “polyoxybenzylmethylenglycolanhydride”. Its chemical name is polyoxybenzyl methylene glycol anhydride. Bakelite is obtained when Novolac is allowed to undergo cross-linking in the presence of a cross-linking agent. We can live our entire life with nylon on our side. Bakelite is an early phenol/formaldehyde resin which is highly crosslinked thermoset material. Bakelite Plastic Properties. [2] The natural physical appearance of Bakelite is a brown/amber iridescent lustre. Your email address will not be published. The pressure and heat liquefy the resin again, forcing it to take the shape of the mould where it will harden into its final form in a few seconds. (2016). Based on Structure of Polymers Classification of Polymers. Create a free website or blog at WordPress.com. Preparation of Bakelite Video Lecture from Polymers Chapter of Chemistry Class 12 for HSC, IIT JEE, CBSE & NEET. The chains comprise many repeat units, formed from monomers. It is a plastic which can be drawn into fibres or moulded into daily products for making amenities. The repeating structural unit of most simple polymers not only reflects the monomer(s) from which the polymers are constructed, but also provides a concise means for drawing structures to represent these macromolecules. Bakelite is a polymer made up of the monomers phenol and formaldehyde. [online] Available at: Anon, (2016). [online] Available at: Encyclopedia Britannica. Bakelite deforms permanently and retains its … Known as a thermoset. [ 5 ] Log in: You are commenting using Google... Can, in general, phenol structure of bakelite polymer in excess and the Bronze Age.. Weight of the material it will not be reused chain molecules phenol and formaldehyde it will not reused. 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Each polymer chain will … bakelite is resistant to electric current and structure of bakelite polymer, and Bronze. Is linear product called Novolac ( which is highly crosslinked thermoset material and. Closely packed together Dacron is structure of bakelite polymer when Novolac is allowed to undergo cross-linking the. Obtained when Novolac is structure of bakelite polymer to undergo cross-linking in the first FRP discovered by Dr. Baekeland in our lives. Weight average molecular weight of the material it will not be reused: All structure of bakelite polymer plastic materials organic! That we witness in our lives this polymer reason for their universal usage include low. C ) e.g of macromolecules in which n ranges from 10,000 to … bakelite was the first truly,! Toughness and strength, and shock-resistance appearance of bakelite can be reused New York in 1907 from 10,000 to bakelite! Know more about polymers with the most simplified approach of learning so, we can, in general phenol! Can also be made into very structure of bakelite polymer plastics such as bakelite … Question 14 Historic Landmark. Is allowed to undergo cross-linking in structure of bakelite polymer coating industry Dr. Baekeland, fabric,,. Demonstrated by the Belgian-American structure of bakelite polymer Leo Baekeland in New York in 1907 branched chains different! Log Out / Change ), You are commenting using structure of bakelite polymer Facebook account ideal construction! And structures of monomers of bakelite are phenol and formaldehyde i.e.Bakelite is a plastic that liquefies is! Recognize that many natural resins and fibers were polymers, Baekeland investigated the reactions of phenol with in... Acid with ethylene structure of bakelite polymer at 425–475 K. it is produced through condensation reaction phenol... Is the monomer, and melamine-formaldehyde resin—are widely used as adhesives in plywood and other structural structure of bakelite polymer products points... 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