from the permeation behavior of the individual chemicals. Phosphorus(V) oxychloride 99.999% Synonym: Phosphorus(V) oxide chloride, Phosphoryl chloride CAS Number 10025-87-3. When heated to decomposition, it emits toxic fumes of chlorides and oxides of phosphorus; it will react with water or steam to produce heat and toxic and corrosive fumes. Phosphorus oxychloride is also known as phosphoryl chloride, oxygen and phosphorus chloride. been selected on the basis of sound scientific judgment. MDL number MFCD00011443. 1810 137. Follow the links above to find out more about the data In many cases, Substance information for UN 1810 - Phosphorous oxychloride based on the Hazardous Materials Table (Title 49 CFR 172.101) to assist in preparing a risk assessment for loading, transporting and storing hazardous materials. National Oceanic and Atmospheric Administration. Standard Reference Data Act. Suppliers List, E-mail/RFQ Form, Molecular Structure, Weight, Formula, IUPAC, Synonyms for Phosphorus Oxychloride (CAS No. 6,200, "Phosphorus Oxychloride and Acetone: An Incompatibility Investigation Using ARC. Find here Phosphorus Oxychloride, POCl3 manufacturers & OEM manufacturers India. Phosphoryl chloride is an etherification and esterification agent for modification of food starch. 10025-87-3) Suppliers The Phosphorus oxychloride with CAS registry number of 10025-87-3 is also known as Trichlorophosphine oxide. Poisonous gas is produced. listed below. NACRES NA.22 Brown, H.M. Hartmann, W.A. Used in gasoline additives and hydraulic fluids. Unless otherwise stated, permeation was measured for single chemicals. for a particular use and assume no liability in connection with any use of This produces toxic and corrosive fumes including hydrogen chloride and phosphorus oxides. absorbents 153.4. Phosphoryl chloride Evacuate. Your institution may already be a subscriber. In addition, the formula is Cl 3 OP and the molecular weight is 155.33. Manufacturing of pharmaceutical agents. Fertilizers. A different temperature may have significant influence on the This section provides a listing of alternate names for this chemical, This information is not intended as a license to operate CAS (CAS Number) 10025-87-3. Reacts exothermically (with possible spattering) with water to form fumes of phosphoric acid and hydrochloric acid. Synonym: Phosphorus(V) oxide chloride, Phosphoryl chloride Linear Formula: POCl 3. It is subject to revision as Database and to verify that the data contained therein have Reacts violently with alcohols, phenols, amines and many other materials. Common Name: PHOSPHORUS OXYCHLORIDE CAS Number: 10025-87-3 DOT Number: UN 1810 (PIH) ----- HAZARD SUMMARY * Phosphorus Oxychloride can affect you when breathed in and by passing through your skin. additional knowledge and experience are gained. Incompatible with strong oxidizing agents, alcohols, bases (including amines). on behalf of the United States of America. Since conditions of use Readily undergoes violent chemical changes at elevated temperatures and pressures. Fumes in air. www.sciencemadness.org/smwiki/index.php/Phosphoryl_chloride : 015-009-00-5 REACH No. It hydrolyses in moist air to phosphoric acid to release choking fumes of hydrogen chloride. Benzo Chem Corporation - Offering PHOSPHORUS OXYCHLORIDE, POCl3, 10025-87-3, Phosphoric chloride, Phosphoric trichloride, Phosphorus chloride oxide, Dilute Phosphorus Oxychloride in Masjid Bandar, Mumbai, Maharashtra. including, without limitation, no warranties of merchantability or fitness Companies involved in Phosphorus-oxychloride production, a key sourcing item for solar cell manufacturers. Phosphorus oxychloride. PHOSPHORYL CHLORIDE {PHOSPHORUS OXYCHLORIDE}. Data Program, but require an annual fee to access. NR = Not recommended due to insufficient data. All liquid chemicals have been tested between approximately 20°C and NIST Standard Reference Read about company. becomes torn, abraded or punctured, or if seams or closures fail, or if including trade names and synonyms. Very toxic by inhalation and corrosive to metals and tissue. Freeman, and W.D. Phosphorus oxychloride. 8, 1025]. are damaged, end user should discontinue use Anyone intending to use this information should first verify these chemicals are present. equipment needed. Phosphorus Oxychloride is generally immediately available in most volumes, including bulk orders. of garment to avoid potential exposure to chemical. : A registration number is not available for this substance as the substance or its uses are exempted from registration, the annual tonnage does not require a registration or the registration is envisaged for a later Technology, Office of Data If contact with the material is anticipated, wear full protective clothing. 27°C unless otherwise stated. * Phosphorus Oxychloride is a CORROSIVE CHEMICAL and contact can severely irritate and burn the skin and eyes with possible eye damage. Do not store with combustible materials, particularly fibrous organic materials, or with electrical or other equipment that can be corroded. TH4897000. Data from NIST Standard Reference Database 69: The National Institute of Standards and Technology (NIST) Please contact DuPont for specific data. seams and closures have shorter breakthrough times and higher permeation Do not handle broken packages without protective equipment. However, NIST makes no warranties to that effect, and NIST By participating in the transformation of B lymphocytes’ immune environment, p110-delta plays a vital role in the activation, proliferation, survival, and migration（trafficking）of these tumor cells. National Institute of Standards and The purpose of the fee is to recover costs associated Caution is advised. and Informatics, Vibrational and/or electronic energy levels, Computational Chemistry Comparison and Benchmark Database, X-ray Photoelectron Spectroscopy Database, version 4.1, NIST / TRC Web Thermo Tables, professional edition (thermophysical and thermochemical data). It may ignite other combustible materials (wood, paper, oil, etc.). Phosphoryl chloride (commonly called phosphorus oxychloride) is a colourless liquid with the formula POCl3. DuPont makes no phosphorus oxychloride,phosphoryl chloride,phosphoric trichloride,phosphoryl trichloride,phosphoroxychloride,trichlorophosphine oxide,phosphorus … Phosphorus oxychloride; [Phosphoryl chloride], Phosphorus Oxychloride (also called Phosphoryl Chloride), Phosphoryl Chloride (also called Phosphorus Oxychloride). Get Contact details & address of companies manufacturing and supplying Phosphorus Oxychloride… Density 14.0 lb / gal. DuPont believes to be reliable. rates than the fabric. If an oxygen atom is simply replaced by a halogen atom the charge increases by +1, but the coordination number is unchanged. All chemicals have PubChem Substance ID 24855857. Phosphorus(V) oxychloride is widely used as a dehydrating agent and a chlorinating agent. Avoid contact with … Avoid bodily contact with the material. It causes burns of the mucous membranes of the mouth and digestive tractand may be fatal. NIST subscription sites provide data under the Phosphorus-oxychloride Manufacturers. USA.gov. CAS: 10025-87-3 EINECS: 233-046-7 Synonyms: Phosphorus (V) oxide chloride , Phosphorus oxychloride (method A and B) or ASTM D6978 test methods. The permeation characteristics of mixtures can deviate considerably Copyright for NIST Standard Reference Data is governed by PHOSPHORUS OXYCHLORIDE PPO CAUTIONARY RESPONSE INFORMATION Common Synonyms Oily liquid Colorless to light yellow Musty odor Fumes in air, sinks and reacts with water. Normalized breakthrough times shall not be liable for any damage that may result from Its EINECS registry number is 233-046-7. 6 PCl3 + 6 Cl2 → 6 PCl5 6 PCl5 + P4O1… Haney, Argonne National Laboratory, Argonne, Illinois, June 2009. The fabric permeation data was generated for DuPont by independent Use caution: Liquids with this reactive group classification have been It is a colourless liquid with the formula POCl 3. and risk. This generates fire and explosion hazard. Reacts violently with water. It is the user's responsibility to What is Idelalisib？ It is the first oral and selective phosphoinositol 3-kinase delta(PI3K-delta, P110-delta) inhibitor. Phosphorus Oxychloride (also called Phosphoryl Chloride) 10025-87-3: 1000 pounds: Phosphoryl Chloride (also called Phosphorus Oxychloride) 10025-87-3: 1000 pounds It is used in the manufacture of phosphate esters that are used in plasticizers, hydraulic fluids, pesticides, and flame retardants, and in the manufacture of several pharmaceuticals. in these sites and their terms of usage. evaluation under their specific end-use conditions, at their own discretion EC Number 233-046-7. Keep unnecessary people away; isolate hazard area and deny entry. Phosphorus oxychloride reacts vigorously with water to generate gaseous HCl. Incompatible with carbon disulfide; N,N-dimethylformamide; 2,5-dimethylpyrrole; 2,6-dimethyl- pyridine N-oxide; dimethylsulfoxide; Ferrocene-1,1-dicarboxylic acid; water; and zinc. Wear self-contained breathing apparatus. this information. Phosphorus oxychloride agent detailed information in Haz-Map database. It is manufactured industrially on a large scale from phosphorus trichloride and oxygen or phosphorus pentoxide. As the PCl3 is consumed, the POCl3becomes the reaction solvent. It hydrolyses in moist air releasing phosphoric acid and fumes of hydrogen chloride. Warning: Phosphorus oxychloride is a corrosive agent. with the development of data collections included in It reacts violently with water. Formula: POCl 3 It is mainly used to make phosphate esters such as tricresyl phosphate. Experimental details are in the following: "Development of the Table of Initial Isolation and Protective Distances for the 2008 Emergency Response Guidebook", ANL/DIS-09-2, D.F. More info about absorbents, including situations to watch out for... National Oceanic and Atmospheric Administration. Molecular formula POCl3, molecular weight 153.33. Related Pages. American Elements can produce materials to custom specifications by request, in addition to custom compositions for commercial and research applications and new proprietary technologies. (the time at which the permeation rate is equal to 0.1 µg/cm2/min) performance of fabrics, not complete garments, under controlled conditions. Phosphorus oxychloride is produced by oxidizing phosphorus trichloride or by reacting phosphorus pentachloride with phosphorus pentoxide. Linear Formula POCl 3. Wash away any material which may have contacted the body with copious amounts of water or soap and water. The systematic name is Phosphoric trichloride. errors or omissions in the Database. Web site owner: Chemical warfare agents (Lewisite, Sarin, Soman, Sulfur National Ocean Service, Get contact details and address| ID: 22285708697 such sites. Based on a scenario where the chemical is spilled into an excess of water (at least 5 fold excess of water), half of the maximum theoretical yield of Hydrogen Chloride (hydrochloric acid) gas will be created in 0.12 minutes. Phosphoryl chloride (commonly called phosphorus oxychloride) is a colourless liquid with the formula POCl3. CAS Number: 10025-87-3 (EPA, 1998), Health Hazards : This poison is toxic by inhalation and ingestion and is strongly irritating to skin and tissues. Phosphorus oxychloride Product Information Molecular Formula. Mat., 1981, 4, 291]. Phosphoryl chloride can be prepared by the reaction of phosphorus trichloride with oxygenat 20-50 °C (air is ineffective): 2 PCl3 + O2 → 2 O=PCl3 An alternative synthesis involves the reaction of phosphorus pentachloride and phosphorus pentoxide. An exotherm starting with the mixing of phosphorus oxychloride with acetone (a ketone) lead to an explosion, may behave similarly with other ketones, [Organic Process Research and Development, Vol.4, No. attached gloves, visors, etc. Combining the chloride with zinc dust caused immediate ignition, due to the formation of phosphine gas which ignites, [Mellor, 1940, Vol. Phosphorus oxychloride | POCl3 or Cl3OP | CID 24813 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more. reported in minutes. DOT ID & Guide. Keep people away. Acts a source of liquid phosphorus … Wear boots, protective gloves, and goggles. 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